One-on-one Definition

wŭnŏn-wŭn, -ôn-
adjective
Consisting of or being direct communication or exchange between two people.
One-on-one instruction.
American Heritage
Contending individually against a single opposing player.
Webster's New World
In direct, personal confrontation.
Webster's New World

(sports) Involving one attacker and one defender.

Wiktionary

(mathematics) Bijective or injective.

Wiktionary
Synonyms:
noun
A game, sport, etc. in which one individual competes against another individual.
Webster's New World
A contest involving only one player on each side, especially of an activity often involving teams.
Why don't we play a little one-on-one until the others show up.
He was willing to go one-on-one with the District Attorney himself.
Wiktionary

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one-on-one