Sentence Examples


  • A historic example is that of the condensation of three molecules of acetone, CH 3 CO CH 3, in the presence of sulphuric acid, to s-trimethylbenzene or mesitylene, C 6 H 3 (CH 3) 3, first observed in 1837 by R.
  • Somewhat similar condensations are: of geranial or citral, (CH 3) 2 CH CH 2 CH :CH C(CH 3) :CH CHO, to p-isopropylmethylbenzene or cymene; of the condensation product of methylethylacrolein and acetone, CH3 CH2 CH:C(CH3) CH:CH CO CH3, to [1.3.
  • 4]-trimethylbenzene or pseudocumene; and of the condensation product of two molecules of isovaleryl aldehyde with one of acetone, C 3 H 7 CH 2 CH:C(C 3 H 7) CH:CH CO.
  • Certain a-diketones condense to form benzenoid quinones, two molecules of the diketone taking part in the reaction; thus diacetyl, CH 3 CO CO CH 3, yields p-xyloquinone, C 6 H 2 (CH 3) 2 0 2 (Ber., 1888, 21, p. 1411), and acetylpropionyl, CH 3 CO CO C 2 H 5, yields duroquinone, or tetramethylquinone, C 6 (CH 3) 4 0 2, Oxymethylene compounds, characterized by the grouping > C:CH(OH), also give benzene derivatives by hydrolytic condensation between three molecules; thus oxymethylene acetone, or formyl acetone, CH 3 CO.
  • CH :CH (OH), formed by acting on formic ester with acetone in the presence of sodium ethylate, readily yields [1.3.51-triacetylbenzene, C 6 H 3 (CO CH 3) 3; oxymethylene acetic ester or formyl acetic ester or ß-oxyacrylic ester, (HO)CH :CH CO 2 C 2 H 51 formed by condensing acetic ester with formic ester, and also its dimolecular condensation product, coumalic acid, readily yields esters of [1.3.
 

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