Sentence Examples

  • 7764 (1890)] decomposes sulphocyanides by fusing with zinc: the zinc is heated with a small quantity of carbon and when completely fused potassium sulphocyanide is added, the mass being well stirred and heated until it thickens and begins to turn red; finally it is allowed to cool out of contact with air, lixiviated with water, the solution decanted, and evaporated to a paste in vacuo.
  • The potassium sulphocyanide is obtained from ammonium sulphocyanide, which is formed by washing crude coal gas with water containing suspended sulphur.
  • Ind., 1893, 13, p. 887) digest carbon bisulphide with ammonia and lime in quantities slightly in excess of those demanded by the following equation: 2CS 2 + 2NH 3 + 2Ca(OH) 2 = Ca(SCN) 2 Ca(SH)2+4H20; the product is then treated with a current of carbon dioxide, calcium carbonate being precipitated, sulphuretted hydrogen escaping, and calcium sulphocyanide remaining in solution.
  • The sulphocyanide is converted into the potassium salt by adding potassium sulphate, and finally desulphurized by lead, zinc, or iron.
  • When heated with alcohol in sealed tubes, it yields carbamic esters; with alcohol and carbon bisulphide at Ioo° C., carbon dioxide is liberated and ammonium sulphocyanide is formed.

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