Thiourea, or sulphocarbamide, CS(NH 2) 2, is formed by prolonged fusion of ammonium thiocyanate (E.
When heated for some time with water to 140° C. in a sealed tube, it is transformed into ammonium thiocyanate, a similar result being obtained by heating the base alone for some hours to 160-170° C. On heating alone for some hours to r70-180° C. it is converted into guanidine thiocyanate.
Thiosemicarbazide, NH 2 CS NH NH 2, prepared from hydrazine sulphate, potassium carbonate and thiocyanate (N.
Chromic thiocyanate, Cr(SCN) 3, an amorphous deliquescent mass, is formed by dissolving the hydroxide in thiocyanic acid and drying over sulphuric acid.
The double thiocyanate, Cr(SCN) 3.3KCNS 4H 2 O, is also known.