Sentence Examples


  • This compound is readily oxidized to benzoic acid, C 6 H 5 000H, the aromatic residue being unattacked; nitric and sulphuric acids produce nitro-toluenes, C6H4 CH3 N02j and toluene sulphonic acids, C 6 H 4 CH 3 SO 3 H; chlorination may result in the formation of derivatives substituted either in the aromatic nucleus or in the side chain; the former substitution occurs most readily, chlor-toluenes, C 6 H 4 CH 3 Cl, being formed, while the latter, which needs an elevation in temperature or other auxiliary, yields benzyl chloride, C 6 H 5 CH 2 C1, and benzal chloride, C 6 11 5 CHC1 2.
  • Phenylnitromethane, C 6 H 5 CH 2 NO 2, isomeric with the nitrotoluenes, is prepared by the action of benzyl chloride on silver nitrite.
  • It is a colourless solid which melts at 92° C. For silicon derivatives of the amines see Michaelis, Ber., 1896, 29, p. 710; on asymmetric silicon and the resolution of dl-benzyl-ethyl-propyl-silicol see F.
  • Those substituted in the benzene nucleus are obtained by condensing two molecules of a substituted benzyl and benzal chlorides.
  • It is formed by the condensation of acetylene tetrabromide with benzene in the presence of aluminium chloride: Br CH Br CH C H +C6H6=4HBr+C6H4) I, )C6H4, Br CH Br CH and similarly from methylene dibromide and benzene, and also when benzyl chloride is heated with aluminium chloride to 200° C. By condensing ortho-brombenzyl bromide with sodium, C. L.

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