The Hydrobromide A' acid results on boiling the A 2 acid on reduction with alkalis, or on eliminating hydroHEXAHYDRO bromic acid from i-brom-cyclo-hexane carboxylic acid-I.
Dihydro Anhydride with acetic anhydride Sodium amalgam in faintly alkaline solution Sodium amalgam (hot) .1 Hydrobromide on reduction Remove H Br from 1.3 Dihydro dibromide Cyclo-heptane Group. Cyclo-heptane (suberane), C 7 H 14, obtained by the reduction of suberyl iodide, is a liquid which boils at 117° C. On treatment with bromine in the presence of aluminium bromide it gives chiefly pentabromtoluene.
The sulphate is still used in medicine, and the British Pharmacopeia has admitted two others, which are much more valuable - the hydrochloride and the acid hydrochloride - whilst the hydrobromide is also used.
While working on the olefines he noticed that a change takes place in the density of the vapour of amylene hydrochloride, hydrobromide, &c., as the temperature is increased, and in the gradual passage from a gas of approximately normal density to one of half-normal density he saw a powerful argument in favour of the view that abnormal vapour densities, such as are exhibited by sal-ammoniac or phosphorus pentachloride, are to be explained by dissociation.
By heating nicotine with bromine in hydrobromic acid solution for some hours at 100° C., dibromticonine hydrobromide, C10H8N2Br202 HBr, results.