Sentence Examples

  • 1848, 65, p. 269) by heating the nitriles of acids with metallic sodium or with sodium ethylate between 130 0 C. and C.
  • It is a most important synthetic reagent; with sodium or sodium ethylate it forms sodio-malonic ester, which reacts readily with alkyl halides, forming alkyl malonic esters, which are again capable of forming sodium derivatives, that by further treatment with alkyl halides yield the di-alkyl malonic esters.
  • CH :CH (OH), formed by acting on formic ester with acetone in the presence of sodium ethylate, readily yields [1.3.51-triacetylbenzene, C 6 H 3 (CO CH 3) 3; oxymethylene acetic ester or formyl acetic ester or ß-oxyacrylic ester, (HO)CH :CH CO 2 C 2 H 51 formed by condensing acetic ester with formic ester, and also its dimolecular condensation product, coumalic acid, readily yields esters of [1.3.
  • Many diketo compounds suffer condensation between two molecules to form hydrobenzene derivatives; thus a, 7 -di-acetoglutaric ester, C 2 H S O 2 C(CH 3 CO) CH CH 2 CH(CO CH 3)CO 2 C 2 H 5, yields a methylketohexamethylene,whiles-acetobutyric ester,CH 3 CO (CH2)2C02C2N5, is converted into dihydroresorcinol or m-diketohexamethylene by sodium ethylate; this last reaction is reversed by baryta (see Decompositions of Benzene Ring).
  • With sodium ethylate in ethyl acetate solution it forms the sodium derivative of benzoyl acetone, from which benzoyl acetone, C6H5.CO.CH2.CO.CH3, can be obtained by acidification with acetic acid.

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