Thallous Perchlorate, T1C10 4, and periodate, Tl10 4, are interesting inasmuch as they are isomorphous with the corresponding potassium salts.
Perchloric acid is best prepared by distilling potassium perchlorate with concentrated sulphuric acid.
The fused mass is then extracted with water to remove potassium chloride, and warmed with hydrochloric acid to remove unaltered chlorate, and finally extracted with water again, when a residue of practically pure perchlorate is obtained.
Soc., 1886, p. 141), the decomposition of potassium chlorate by heat is not at all simple, the quantities of chloride and perchlorate produced depending on the temperature.
It crystallizes in dark purple-red prisms, isomorphous with potassium perchlorate.