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This acid with silver nitrite gave nitroacetic acid, which readily gave the second nitromethane, CH a (NO 2) b H c H d, identical with the first nitromethane.
This acid gives with silver nitrite the corresponding nitromalonic acid, which readily yielded the third nitromethane, CHaHb(N02),Hd, also identical with the first.
When methyl iodide is used, nitromethane is the sole product, but the higher homologues give more or less of the isomeric nitrous esters.
This readily gave with silver nitrite a nitromethane in which we may suppose the nitro-group to replace the a hydrogen atom, i.e.
The fourth nitromethane was obtained from the nitromalonic acid previously mentioned by a repetition of the method by which the third was prepared; this was identical with the other three.
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