This base is resolved into its active components by d-tartaric acid, l-nicotine-d-tartrate crystallizing out first.
Of potassium acid tartrate; (d) potassa sulphurata (liver of sulphur), a mixture of salts of which the chief are sulphides of potassium; (e) sulphuris iodidum (U.S.P.), which has a preparation unguentum sulphuris iodidi, strength 1 in 25.
Tartaric acid, which is sometimes present in large quantities as an adulterant in commercial citric acid, may be detected in the presence of the latter, by the production of a precipitate of acid potassium tartrate when potassium acetate is added to a cold solution.
Another mode of separating the two acids is to convert them into calcium salts, which are then treated with a perfectly neutral solution of cupric chloride, soluble cupric citrate and calcium chloride being formed, while cupric tartrate remains undissolved.
Citric acid is also distinguished from tartaric acid by the fact that an ammonia solution of silver tartrate produces a brilliant silver mirror when boiled, whereas silver citrate is reduced only after prolonged ebullition.