In light Kundt's name is widely known for his inquiries in anomalous dispersion, not only in liquids and vapours, but even in metals, which he obtained in very thin films by means of a laborious process of electrolytic deposition upon platinized glass.
It may be prepared by distilling fuming sulphuric acid, or concentrated sulphuric acid over phosphorus pentoxide, or by the direct union of sulphur dioxide with oxygen in the presence of a catalyst, such as platinized asbestos (see Sulphuric Acid).
Dennstedt, which was first proposed in 1902, the substance is vaporized in a tube containing at one end platinum foil, platinized quartz, or platinized asbestos.
648) burns the substance in oxygen, conducts the gases over platinized sand, and collects the products in suitable receivers.
It is also prepared by heating ammonium nitrite (or a mixture of sodium nitrite and ammonium chloride): NH 4 NO 2 =2H20+N21 by heating a mixture of ammonium nitrate and chloride (the chlorine which is simultaneously produced being absorbed by milk of lime or by a solution of sodium hydroxide): 4NH4N03+2NH4C1=5N2 +C1 2 +12H 2 O; by heating ammonium dichromate (or a mixture of ammonium chloride and potassium dichromate): (NH4)2Cr207 = Cr203+4H20+ N2; by passing chlorine into a concentrated solution of ammonia (which should be present in considerable excess): 8NH3+3C12=6NH4C1-F-N2; by the action of hypochlorites or hypobromites on ammonia: 3NaOBr-+2NH 3 =3NaBr+3H 2 OH-N 2; and by the action of manganese dioxide on ammonium nitrate at 180-20oÂ° C. It is also formed by the reduction of nitric and nitrous oxides with hydrogen in the presence of platinized asbestos at a red heat (G.
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