Sentence Examples

  • Molybdenum trisulphide, MoS3, is obtained by saturating a solution of an alkaline molybdate with sulphuretted hydrogen and adding a mineral acid.
  • Ann., 1826, 8, p. 23), by converting lead molybdate into lead nitrate, obtained the value 95.
  • Of other lead minerals we may mention the basic sulphate lanarkite, PbO PbSO 4; leadhillite, PbSO 4.3PbCO 3; the basic chlorides matlockite, PbO PbC12j and mendipite, PbC1 2.2PbO; the chloro-phosphate pyromorphite, PbC12.3Pb3(P04)2, the chloro-arsenate mimetesite, PbC12.3Pb3(As04)2; the molybdate wulfenite, PbMoO 4; the chromate crocoite or crocoisite, PbCrO 4; the tungstate stolzite, PbW04.
  • Other precipitants of phosphoric acid or its salts in solution are: ammonium molybdate in nitric acid, which gives on heating a canary-yellow precipitate of ammonium phosphomolybdate, 12[M00 3] (NH 4) 3 PO 4, insoluble in acids but readily soluble in ammonia; magnesium chloride, ammonium chloride and ammonia, which give on standing in a warm place a white crystalline precipitate of magnesium ammonium phosphate, Mg(NH 4)PO 4.6H 2 0, which is soluble in acids but highly insoluble in ammonia solutions, and on heating to redness gives magnesium pyrophosphate, Mg 2 P 2 0 7; uranic nitrate and ferric chloride, which give a yellowish-white precipitate, soluble in hydrochloric acid and ammonia, but insoluble in acetic acid; mercurous nitrate which gives a white precipitate, soluble in nitric acid, and bismuth nitrate which gives a white precipitate, insoluble in nitric acid.
  • There are several volumetric methods for assaying lead ores, but the best known is that based on the precipitation of lead by ammonium molybdate in an acetic acid solution.