Sentence Examples


  • The osazone prepared from a-acrose resembled most closely the glucosazone yielded by glucose, mannose, and fructose, but it was optically inactive; also the ketose which it gave after treatment with hydrochloric acid and reduction of the osone was like ordinary fructose except that it was inactive.
  • The acid yields, on appropriate treatment, d-mannose and d-mannite.
  • The identity of the formulae and osazones of d-mannose and d-glucose showed that the stereochemical differences were situated at the carbon atom adjacent to the aldehyde group. Fischer applied a method indicated by Pasteur in converting dextro into laevo-tartaric acid; he found that both d-mannonic and d-gluconic acids (the latter is yielded by glucose on oxidation) were mutually convertible by heating with quinoline under pressure at 140°.
  • Fischer's a-acrose therefore led to the synthesis of the dextro and laevo forms Gf mannose, glucose and fructose; and these substances have been connected synthetically with many other sugars by means of his cyanhydrin process, leading to higher sugars, and Wohl and.
  • Certain of these relations are here summarized (the starting substance is in italics): l-Glucose f- 1-arabinose --- l-mannose - l-mannoheptose; glucononose fa-gluco-octose F - a-glucoheptose f- d-glucose - 0-glucoheptose - > /-gluco-octose; d-mannose--> d-mannoheptose--> manno-octose--> mannononose; d-glucose --> d-arabinose - i d-erythrose.
 

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