Sentence Examples

  • It is a crystalline solid which melts at 56° C. and boils at 204° C. It can only be diazotized in the presence of concentrated sulphuric acid, and even then the free diazonium sulphate is not stable, readily passing in the presence of water to a-oxypyridine.
  • Pechmann, Ber., 18 9 5, 28, p. 857); by distilling anisic acid (paramethoxy benzoic acid) with baryta or by boiling phenyl diazonium chloride with methyl alcohol.
  • Hantzsch (Ber., 1901, 34, p. 3337) has shown that in the action of alcohols on diazonium salts an increase in the molecular weight of the alcohol and an accumulation of negative groups in the aromatic nucleus lead to a diminution in the yield of the ether produced and to the production of a secondary reaction, resulting in the formation of a certain amount of an aromatic hydrocarbon.
  • OH N02(1.4), crystallizes in long colourless needles which melt at 114°C. Meta-nitrophenol, C6H4.OH N02 (1.3), is prepared from meta-nitraniline by diazotizing the base and boiling the resulting diazonium salt with water.
  • Nitro compounds have also been prepared by the action of cuprous oxide on diazonium salts (T.

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