Sentence Examples


  • It is a liquid which boils at 82° C. Hypochlorous acid converts it into 2-chlor-cyclo-hexanol-I, whilst potassium permanganate oxidizes it to cyclo-hexandi-ol.
  • This acid when heated with concentrated hydrochloric acid to 120-130° C. yields a chlor-acid, which on warming with alcoholic potash is transformed into the cyclo-heptene compound.
  • Chlor-, brom-, iodoand fluor-benzoic acids are known and can be obtained by oxidizing the corresponding halogen toluenes, or from the amido acids, or by substitution.
  • It may also be prepared by oxidizing benzyl alcohol with concentrated nitric acid; by distilling a mixture of calcium benzoate and calcium formate; by the condensation of chlor-oxalic ester with benzene in the presence of aluminium chloride, the ester of the ketonic acid formed being then hydrolysed and the resulting acid distilled: C 6 H 6 +Cl CO Cooc 2 H 5 = C,H5co COOC2H5d-HC1, C 6 H 5 CO 000H =C6H5CHO+C02; by the action of anhydrous hydrocyanic acid and hydrochloric acid on benzene, an aldime being formed as an intermediate product: C 6 H 6 +HCN+HC1= C6H5CH :NH HC1, Benzaldine hydrochloride C 6 H 5 CH: NH HC1+H 2 O =NH4C1+C6H5CHO; and by the action of chromium oxychloride on toluene dissolved in carbon bisulphide (A.
  • The co-chlor compound results when, (3-phenyl-a-chlorlactic acid (from hypochlorous acid and cinnamic acid) is heated with water; it has a hyacinthine odour and yields phenylacetaldehyde when heated with water.
 

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