The osazone prepared from a-acrose resembled most closely the glucosazone yielded by glucose, mannose, and fructose, but it was optically inactive; also the ketose which it gave after treatment with hydrochloric acid and reduction of the osone was like ordinary fructose except that it was inactive.
It crystallizes in colourless prisms and is optically active.
Since the molecule contains an asymmetric carbon atom, the acid exists in three forms, one being an inactive "racemic" mixture, and the other two being optically active forms. The inactive variety is known as paramandelic acid.
If the configuration of d-saccharic acid were given by either 6 or To, bearing in mind the relation of mannose to glucose, it would then be necessary to represent d-mannosaccharic acid by either 7 or 8 - as the forms 6 and Io pass into 7 and 8 on changing the sign of a terminal group; but this cannot be done as mannosaccharic acid is optically active.
Hence it follows that the " optical " formulae of the acids derived from two pentoses having the configuration given above will be C02H - 0 - C02H CO 2 H + 0 - C02H, and that consequently only one of the acids will be optically active.
