They behave in most respects as unsaturated compounds; they combine with hydrogen to form amines; with water to form acidamides; with sulphuretted hydrogen to form thio-amides; with alcohols, in the presence of acids, to form imido-ethers R C(:NH) OR'; with ammonia and primary amines to form amidines R C(:NH) NH 2 i and with hydroxylamine to form amidoximes, R C(:NOH) NH 2.
They may be prepared by converting nitriles into amidoximes by the action of hydroxylamine, the amidoximes so formed being then acylated by acid chlorides or anhydrides.
The carbonyl oxygen may also be replaced by the oxime group,: N OH; thus the acids yield the hydroxamic acids, R C(OH): NOH, and the acid-amides the amidoximes, R C(NH 2): NOH.
Closely related to the amidoximes are the nitrolic acids, R C(NO 2): NOH.
How would you define amidoximes? Add your definition here.
